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Templating Self-Assembly

Block copolymer templated by lithographically defined silica posts
Lithography is currently being squeezed between two engineering realities: an extraordinary requirement on resolution for nanoscale manufacturing, and an extraodinary length of time required to form master patterns for nanostructures (by conventional electron-beam lithography). Templating allows much lower-density master patterns to yield complex and controlled self-assembled structures. The result is a technique that bridges lithography and chemistry to realize a whole new kind of nanopatterning.

Recent Publications

Graphoepitaxy of Self-Assembled Block Copolymers on Two-Dimensional Periodic Patterned Templates

Bottom-up meets top-down: templating of self-assembly is used to achieve long-range order. Typically block copolymers self-assemble into partially-ordered arrays of structures (in our case ~20-nanometer-diameter spheres of silica) on a substrate. But by including some lithographic posts on the substrate prior to applying the copolymer, we were able to realize well-ordered arrays with controlled orientations that covered large areas on the substrate.
Scanning-electron micrograph of self-assembled block copolymers (grey) after selective removal of one block component, templated by lithographically-defined posts (white).

Ion Bita, Joel K. W. Yang, Yeon Sik Jung, Caroline A. Ross, Edwin L. Thomas, and Karl K. Berggren, Science vol. 321, pp. 939 (2008) [link to publications page for electronic access].

Collaborators

  • Prof. Caroline A. Ross (MIT)
  • Prof. Edwin L. Thomas (MIT)
  • Prof. Vladimir Bulovic (MIT)

Additional Information

Coverage in the popular press:

Sponsors

  • National Research Initiative, INDEX program
  • King Abdulaziz City for Science and Technology (KACST) and Al'Faisal University

 

 

 
 
       
 
 
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Quantum Nanostructures and Nanofabrication Group Prof. Karl K. Berggren